Technology

June 21, 2021

Huntsman Introduces New TPU Grade



NEW IROGRAN® TPU GRADE FROM HUNTSMAN HAS IMPROVED PROPERTIES FOR FIRE HOSES AND TEXTILES

THE WOODLANDS, TX– Specialty Elastomers experts from Huntsman have developed a new thermoplastic polyurethane (TPU) grade for technical extrusion parts and blown film applications that offers significant improvements over previous generation technologies when it comes to durability, production efficiency and reducing manufacturing waste. IROGRAN® A 85 P 4394 HR TPU is the latest addition to a well-established family of elastomer products from Huntsman, which are renowned for their performance in a diverse range of industrial and consumer applications.

Developed in close partnership with Huntsman’s customers, IROGRAN® A 85 P 4394 HR TPU has greater tensile strength than the standard IROGRAN® A 85 P 4394 elastomer grade originally developed in 2004. The new grade also offers improved film extrusion quality and high melt strength, which makes it ideal for blown film applications. Delivering better resistance to force in its melted state, which makes it less likely that an extruded film will break during production, IROGRAN® A 85 P 4394 HR TPU can help to significantly lower scrap rates, improve manufacturing throughput and cut waste in blown film processing.

IROGRAN® A 85 P 4394 HR TPU is developed to solve the problems of customers in diverse markets including: 

  • TPU lay flat hoses used in high pressure industrial and municipal applications e.g., firefighting
  • Textile lamination – as a breathable, waterproof layer for rugged performance apparel.

In the manufacture of TPU lay flat hoses, IROGRAN® A 85 P 4394 HR TPU is applied via the “extrusion through-the-weave” process. In this application, the product’s greater tensile strength is highly advantageous – helping the resulting hoses cycle between periods of being tightly coiled and then extended and put under high water pressure levels. In the case of fire hoses, this pressure can typically be in the region of 8 and 20 bar (800 and 2000 kPa; 116 and 290 psi).

When it comes to textile lamination, IROGRAN® A 85 P 4394 HR TPU is an excellent material for creating a waterproof, breathable film in rugged performance apparel (including gloves and footwear). Blown to create an extremely thin layer, which is then added to fabrics, IROGRAN® A 85 P 4394 HR TPU provides the protective properties needed to create high performance outdoor garments. Adhering well to different kinds of fabrics, IROGRAN® A 85 P 4394 HR TPU can aid the stretch and recovery of the materials it is used on. The nature of the grade also means the resulting films can be engineered to have different surface finishes, including gloss, smooth and matte effects

Trent Shidaker, Global Marketing Director, Elastomers at Huntsman, said: “IROGRAN® A 85 P 4394 HR TPU is a highly versatile and durable elastomer. Soft to the touch, it’s ideal for apparel applications that need to stay in contact with the wearer for hours at a time; but it’s also strong enough to be used in municipal and industrial hoses that have to perform under the toughest conditions. Applying its development expertise, our elastomers team has enhanced the processing properties of IROGRAN® A 85 P 4394 HR TPU, without compromising the key performance attributes expected of products in this range – namely excellent hydrolytic resistance; fantastic wear performance; and microbial resistance. The result is an elastomer that can enable manufacturers to work more efficiently, cut waste and create longer-lasting products; a compelling proposition for the markets we serve.”

The basis of the chemistry of IROGRAN® A 85 P 4394 HR TPU goes back to 2004 when the flagship product was first developed. Later variations of the product were developed to create the family of elastomer products from Huntsman that customers have learned to know and love.  

Other IROGRAN® A 85 P 4394 TPU products available from Huntsman include:

  • IROGRAN® A 85 P 4394 – a legacy product, launched in 2004, that was first introduced for thin wall technical parts, thin wall extrusion profiles, spiral hoses, cable jacketing and film and sheet
  • IROGRAN® A 85 P 4394 FCM – launched in 2015, this grade has a similar base chemistry to the standard version of IROGRAN® A 85 P 4394 but is formulated with raw materials that are compliant with FDA regulations for food processing belts and has an NSF 61 rating (approved for potable water applications).
  • IROGRAN® A 85 P 4394 UV – also launched in 2015, this product is fortified with proprietary additives that enable it to withstand UV exposure while maintaining excellent physical properties and appearance. This product is used for pneumatic tubing for airlines and industrial equipment and fracking hoses.

IROGRAN® A 85 P 4394 HR TPU is made at the Huntsman Polyurethanes manufacturing facility in Ringwood Illinois. For more information about the full range of IROGRAN A 85 P 4394 TPU products available from Huntsman, please contact: joanna_marzec@huntsman.com.

June 21, 2021

Huntsman Introduces New TPU Grade



NEW IROGRAN® TPU GRADE FROM HUNTSMAN HAS IMPROVED PROPERTIES FOR FIRE HOSES AND TEXTILES

THE WOODLANDS, TX– Specialty Elastomers experts from Huntsman have developed a new thermoplastic polyurethane (TPU) grade for technical extrusion parts and blown film applications that offers significant improvements over previous generation technologies when it comes to durability, production efficiency and reducing manufacturing waste. IROGRAN® A 85 P 4394 HR TPU is the latest addition to a well-established family of elastomer products from Huntsman, which are renowned for their performance in a diverse range of industrial and consumer applications.

Developed in close partnership with Huntsman’s customers, IROGRAN® A 85 P 4394 HR TPU has greater tensile strength than the standard IROGRAN® A 85 P 4394 elastomer grade originally developed in 2004. The new grade also offers improved film extrusion quality and high melt strength, which makes it ideal for blown film applications. Delivering better resistance to force in its melted state, which makes it less likely that an extruded film will break during production, IROGRAN® A 85 P 4394 HR TPU can help to significantly lower scrap rates, improve manufacturing throughput and cut waste in blown film processing.

IROGRAN® A 85 P 4394 HR TPU is developed to solve the problems of customers in diverse markets including: 

  • TPU lay flat hoses used in high pressure industrial and municipal applications e.g., firefighting
  • Textile lamination – as a breathable, waterproof layer for rugged performance apparel.

In the manufacture of TPU lay flat hoses, IROGRAN® A 85 P 4394 HR TPU is applied via the “extrusion through-the-weave” process. In this application, the product’s greater tensile strength is highly advantageous – helping the resulting hoses cycle between periods of being tightly coiled and then extended and put under high water pressure levels. In the case of fire hoses, this pressure can typically be in the region of 8 and 20 bar (800 and 2000 kPa; 116 and 290 psi).

When it comes to textile lamination, IROGRAN® A 85 P 4394 HR TPU is an excellent material for creating a waterproof, breathable film in rugged performance apparel (including gloves and footwear). Blown to create an extremely thin layer, which is then added to fabrics, IROGRAN® A 85 P 4394 HR TPU provides the protective properties needed to create high performance outdoor garments. Adhering well to different kinds of fabrics, IROGRAN® A 85 P 4394 HR TPU can aid the stretch and recovery of the materials it is used on. The nature of the grade also means the resulting films can be engineered to have different surface finishes, including gloss, smooth and matte effects

Trent Shidaker, Global Marketing Director, Elastomers at Huntsman, said: “IROGRAN® A 85 P 4394 HR TPU is a highly versatile and durable elastomer. Soft to the touch, it’s ideal for apparel applications that need to stay in contact with the wearer for hours at a time; but it’s also strong enough to be used in municipal and industrial hoses that have to perform under the toughest conditions. Applying its development expertise, our elastomers team has enhanced the processing properties of IROGRAN® A 85 P 4394 HR TPU, without compromising the key performance attributes expected of products in this range – namely excellent hydrolytic resistance; fantastic wear performance; and microbial resistance. The result is an elastomer that can enable manufacturers to work more efficiently, cut waste and create longer-lasting products; a compelling proposition for the markets we serve.”

The basis of the chemistry of IROGRAN® A 85 P 4394 HR TPU goes back to 2004 when the flagship product was first developed. Later variations of the product were developed to create the family of elastomer products from Huntsman that customers have learned to know and love.  

Other IROGRAN® A 85 P 4394 TPU products available from Huntsman include:

  • IROGRAN® A 85 P 4394 – a legacy product, launched in 2004, that was first introduced for thin wall technical parts, thin wall extrusion profiles, spiral hoses, cable jacketing and film and sheet
  • IROGRAN® A 85 P 4394 FCM – launched in 2015, this grade has a similar base chemistry to the standard version of IROGRAN® A 85 P 4394 but is formulated with raw materials that are compliant with FDA regulations for food processing belts and has an NSF 61 rating (approved for potable water applications).
  • IROGRAN® A 85 P 4394 UV – also launched in 2015, this product is fortified with proprietary additives that enable it to withstand UV exposure while maintaining excellent physical properties and appearance. This product is used for pneumatic tubing for airlines and industrial equipment and fracking hoses.

IROGRAN® A 85 P 4394 HR TPU is made at the Huntsman Polyurethanes manufacturing facility in Ringwood Illinois. For more information about the full range of IROGRAN A 85 P 4394 TPU products available from Huntsman, please contact: joanna_marzec@huntsman.com.

June 9, 2021

Bio Butanediol Project

Bio-BDO venture by Cargill and Helm

9 June 2021 – 0 Submitted by Andrew Warmington

Agribusiness giant Cargill and German chemical marketing and distribution firm Helm have formed a joint venture called Qore and will invest $300 million to build the first commercial-scale, renewable 1,4-butanediol (BDO) facility in the US. This will be located at Cargill’s biotechnology campus and corn refining operation in Eddyville, Iowa, and should be in operation in 2024.

Qore has licensed Genomatica’s BDO process technology and is using Cargill’s global feedstock supply and fermentation manufacturing expertise to produce at least 65,000 tonnes/year, under the brand name Qira. Helm will work with brand owners, OEMs and their suppliers to incorporate Qira into their products.

Qira is made via the fermentation of plant-based sugars and it is claimed, can reduce greenhouse gas emissions by 93% compared to the manufacture of the same chemical intermediates from fossil sources. Applications include fibres, biodegradable plastics, polyurethane coatings, sealants and artificial leathers.

https://www.specchemonline.com/bio-bdo-venture-cargill-and-helm

June 9, 2021

Bio Butanediol Project

Bio-BDO venture by Cargill and Helm

9 June 2021 – 0 Submitted by Andrew Warmington

Agribusiness giant Cargill and German chemical marketing and distribution firm Helm have formed a joint venture called Qore and will invest $300 million to build the first commercial-scale, renewable 1,4-butanediol (BDO) facility in the US. This will be located at Cargill’s biotechnology campus and corn refining operation in Eddyville, Iowa, and should be in operation in 2024.

Qore has licensed Genomatica’s BDO process technology and is using Cargill’s global feedstock supply and fermentation manufacturing expertise to produce at least 65,000 tonnes/year, under the brand name Qira. Helm will work with brand owners, OEMs and their suppliers to incorporate Qira into their products.

Qira is made via the fermentation of plant-based sugars and it is claimed, can reduce greenhouse gas emissions by 93% compared to the manufacture of the same chemical intermediates from fossil sources. Applications include fibres, biodegradable plastics, polyurethane coatings, sealants and artificial leathers.

https://www.specchemonline.com/bio-bdo-venture-cargill-and-helm

May 17, 2021

Wind Turbine Blade Recycling Project

New-Technology-for-Full-Recyclability-of-Wind-Turbine-Blades

Home/Environment/New Technology for Full Recyclability of Wind Turbine Blades Environment

New Technology for Full Recyclability of Wind Turbine Blades

Energy Industry Review4 hours agoLast Updated: May 17, 2021 30 4 minutes read

A coalition of industry and academic leaders have developed a new technology to enable circularity for thermoset composites, the material used to make wind turbine blades. The new technology delivers the final technological step on the journey towards a fully recyclable wind turbine value chain. To enable the adoption of this new technology, and to advance a circular economy across the wind industry, a new initiative entitled CETEC (Circular Economy for Thermosets Epoxy Composites) has been established. Within three years, CETEC is aiming to present a fully scoped solution ready for industrial adoption, based on commercialisation of the novel circularity technology.

Partly funded by Innovation Fund Denmark (IFD), CETEC is spearheaded by Vestas, the global leader in sustainable energy solutions, and involves both industrial and academic leaders including Olin, the world leading producer of Epoxy, the Danish Technological Institute (DTI), and Aarhus University.

Developed by DreamWind, an innovation initiative driven by the same partners, the new technology consists of a two-step process. Firstly, thermoset composites are disassembled into fibre and epoxy. Secondly, through a novel chemcycling process, the epoxy is further broken up into base components similar to virgin materials. These materials can then be reintroduced into the manufacturing of new turbine blades, constituting a new circularity pathway for epoxy resin.

Wind turbines are 85-90 percent recyclable, with turbine blades material constituting the remaining percentage that cannot be recycled, due to the nature of thermoset composites. CETEC is aiming to close this recycling gap and enable a significant step forward in the elimination of waste across the wind energy industry.

“As global commitments to a net-zero future increase, it’s absolutely crucial to ensure the wind industry can scale sustainably, which includes Vestas fulfilling our ambition to produce zero-waste turbines by 2040. Leveraging this new technological breakthrough in chemcycling epoxy resin, the CETEC project will be a significant milestone in Vestas’ journey towards achieving this goal, and in enabling a future where landfill is no longer required in blade decommissioning,” said Allan Korsgaard Poulsen, Head of Sustainability and Advanced Materials, Vestas Innovation and Concepts.

“The key characteristic of composite materials is their unique combination of low weight and high strength. This is governed by the strong bonding of two different materials – fibre and epoxy. The dilemma is that this strong bond is also the feature that renders these materials difficult to recycle. Therefore, the development of CETEC’s novel technology, enabling disassembly of the composite at end-of-life, is a gamechanger, that will allow us to capture the value represented by each material stream in a new circular value chain”, said Simon Frølich, Team Manager, PhD, Danish Technological Institute.

“Chemcycling of epoxy-based materials would allow deconstructing these highly stable polymer chains into molecular building blocks. These building blocks are easily processable and can be utilised to produce new epoxy, which will have the same quality as the original material. Avoiding the loss of valuable molecular complexity in such a way is a highly desirable concept and an important step to sustainable materials,” said Prof. Dr. Troels Skrydstrup, Aarhus University.

CETEC’s solution will address the lack of available recycling technology for epoxy resins. This would in turn create the possibility to introduce new recycling solutions to the wind industry. This holds significant potential for commercial value capture, particularly in markets where regulation around waste management for manufacturing industries is tightening to serve a broader sustainability agenda. When fully developed, the solution may also have an impact for other industries that rely on thermoset composite in production, such as automotive and aviation.

“As the leading Epoxy producer and global supplier for the wind industry, Olin is proud to provide our technological expertise to this important sustainability project,” said Leif Ole Meyer, TS&D Leader EMEAI at Olin. “To develop technologies which close an existing gap of thermosets by creating a circularity is yet another example of putting our Resource Efficiency sustainability goal into action. This innovation will help the industry to minimize consumption of virgin material sources and increase the reuse and recycling of materials.”

About Danish Technological Institute

Danish Technological Institute (DTI) is an independent research and development institute. It takes an innovative approach to improving the competitiveness of business and industry, society and public life. With more than 12,000 customers in 65 countries, they develop new knowledge through research and development activities in close corporation with Danish and international companies and research institutes.

About Aarhus University

Aarhus University is a globally oriented, academically diverse, and research-intensive university. Aarhus University ranks among the top 100 universities in the world on several of the most important international ranking lists, out of over 17,000 universities worldwide. Around 12 per cent of AU’s 40.000 students are international, representing over 120 nationalities. Aarhus University offers state-of-the-art facilities and laboratories having a strong tradition of multidisciplinary research for instance in one of its 42 major research centres. The university’s goal is to contribute towards solving the complex global challenges facing the world. The university therefore strives to combine the high level of academic standards of its researchers with collaboration across disciplinary boundaries to combine research in new ways and solve challenges in close contact with the world around us.

About Olin

With over 8,000 employees globally and almost 130 years in business, Olin Corporation is the world’s chlor-alkali leader, including epoxy products and chlorinated organics. Olin’s regional headquarters for Europe, Middle East, Africa, and India is based in Zug, Switzerland. The company employs over 650 professionals in its European offices, research, and innovation centres, and manufacturing locations in Baltringen, Rheinmunster and Stade, Germany, Pisticci, Italy, and Terneuzen, Netherlands. Olin is committed to exceeding customer expectations through operational and commercial excellence, innovation capabilities and quality people who serve their valued customers.

About Vestas

Vestas is the energy industry’s global partner on sustainable energy solutions. They design, manufacture, install, and service onshore and offshore wind turbines across the globe, and with more than 136 GW of wind turbines in 84 countries, Vestas has installed more wind power than anyone else. Through its industry-leading smart data capabilities and unparalleled more than 117 GW of wind turbines under service, Vestas uses data to interpret, forecast, and exploit wind resources and deliver best-in-class wind power solutions. Together with their customers, Vestas’ more than 29,000 employees are bringing the world sustainable energy solutions to power a bright future.

https://energyindustryreview.com/environment/new-technology-for-full-recyclability-of-wind-turbine-blades/